Risuki is actually surprised when she sees the anger built up in Asahi, an emotion she hadn't really seen him show often before at all. She'd seen him bored, disappointed, and happy, even the terror when he'd been caught in the scorpion breeding pen before, but now she was seeing this rage inside him for his inability to save the scorpions that the bandits had been stealing, and in a sense torturing them by stealing as much of their venom as they could. She can also see him reining in his emotions in order to not get himself and his teammate into trouble by acting in haste and anger, which would not only likely end with their mission being a failure, but also making the next mission to likely take out the bandits even harder, if not impossible with the bandits aware of the fact that Sunagakure knows of their plots.
She pauses as she's told that they're either selling the venom, or using it themselves, harvesting the venom themselves instead of stealing the venom. This was extremely helpful information, and would definitely ensure that the next team to go after the bandits would need to be careful to avoid getting themselves poisoned by their weapons. After this revelation, he asks what she'd learned, and she answers him simply, but with a detailed understanding of their plans for what they see as a war with Sunagakure.
"They plan to take out the Katsue clan first, as they're the ones with access to the original venom as well as the antidote for their own scorpions' venom. Next, they plan to attack Sunagakure indirectly, by envenomating various people to make it look like the start of an illness, before getting one of their own number sick to get him sent to the medical corps, and from there will help the other bandits in so they can take out the medical corps. From there, they hoped to take out all of Sunagakure... We better hurry back home, or we'll be too late to come up with a plan against them."
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